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- W2056271903 endingPage "1680" @default.
- W2056271903 startingPage "1680" @default.
- W2056271903 abstract "Multivalent carbohydrate ligands have been prepared by assembling α-cyclodextrin-based pseudo-rotaxanes through “click chemistry”. The inclusion complex formed by a lactosyl-α-CD conjugate and a decane axle carrying a lactosyl stopper at one extremity and an azido group at the other end was dimerized by bis-propargyl spacers of different lengths to provide oligorotaxanes having adjustable threading ratios. For the first time, saccharidic ligands have been introduced on rotaxanes both as a biological recognition element and as a capping group. The supramolecular species have been isolated and characterized by mass spectrometry as well as by 1D and DOSY NMR experiments. Their ability to inhibit the binding of Arachis hypogaea agglutinin to asialofetuin, assayed by enzyme linked lectin assays (ELLA), was shown to be valency-dependent." @default.
- W2056271903 created "2016-06-24" @default.
- W2056271903 creator A5028248981 @default.
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- W2056271903 creator A5081141895 @default.
- W2056271903 date "2009-01-01" @default.
- W2056271903 modified "2023-10-10" @default.
- W2056271903 title "Synthesis and biological evaluation of multivalent carbohydrate ligands obtained by click assembly of pseudo-rotaxanes" @default.
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- W2056271903 doi "https://doi.org/10.1039/b822976g" @default.
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