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- W2056293432 abstract "Adsorption isotherms of n-octane and toluene were measured on thermally treated controlled porosity glasses (CPG) and on boron-coated silica gel (SG). From the isotherms the film pressure (π) for both adsorbates was determined. Based on extrapolated πmax values the dispersion (γdS) and the non-dispersion (γnS) components of the surface free energy for all the investigated materials were calculated. It was found that the changes in γdS caused by the surface modification were relatively small (∼ 4mJ/m2), while those of γnS were significant. The boron compounds decrease the γnS value from 145–160 to 37–55 mJ/m2. The dependences between δπ/δa and the adsorbed amount can give some suggestion about the adsorption mechanism and surface homogeneity. The presence of Na on the surface of both CPG and SG seems to be a more important factor for adsorption than that of boron. The significant changes in non-dispersion interactions were attributed to surface dehydroxylation, which may result from both the thermal treatment and the presence of boron on the surface." @default.
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- W2056293432 date "1991-01-01" @default.
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- W2056293432 title "Investigation of the surface free energy components of thermally treated controlled porosity glasses by inverse gas chromatography" @default.
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- W2056293432 doi "https://doi.org/10.1016/0169-4332(91)90106-t" @default.
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