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- W2056319685 abstract "Self-assembly of cylinder-forming diblock copolymers under spherical confinement is studied using real-space self-consistent field theory calculations (SCFT). Various microstructures are found at different confinement dimensions and surface fields. Most of these microstructures are center-symmetric and they could not be formed in bulk or under planar and cylindrical confinements. It is also observed that the interactions between the confinement surface and the polymers have a large effect on the self-assembly. When the spherical confinement’s surface attracts the short blocks, the self-assembled structures become similar to those under a neutral surface field. On the other hand, when the spherical confinement’s surface attracts the long blocks, the equilibrium structures become different from those under a neutral surface field." @default.
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- W2056319685 date "2008-10-29" @default.
- W2056319685 modified "2023-10-05" @default.
- W2056319685 title "Microstructures of a Cylinder-Forming Diblock Copolymer under Spherical Confinement" @default.
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- W2056319685 doi "https://doi.org/10.1021/ma800443h" @default.
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