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- W2056321837 endingPage "1518" @default.
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- W2056321837 abstract "Propargyl glyco 1,2-orthoesters were exploited for the efficient synthesis of interesting glycomonomers such as glyco-acrylates and acrylamides using gold catalysts. It was observed that propargyl glyco 1,2-orthoesters with hydroxyethyl acrylates gives very good yield of the corresponding glyco-acrylates in a single step in the presence of catalytic amount of gold(III) catalyst; whereas, gold catalyzed glycosidation reaction on hydroxyethyl acrylamides was found to yield the corresponding acrylamidoyl 1,2-orthoester which was then converted to the corresponding glycol-acrylamide in the presence of catalytic amount of TMSOTf. Synthesized glyco-acrylate/acrylamide monomers are shown to undergo thiolate addition as well as free radical polymerization." @default.
- W2056321837 created "2016-06-24" @default.
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- W2056321837 date "2011-09-01" @default.
- W2056321837 modified "2023-10-16" @default.
- W2056321837 title "Gold catalyzed glycosidations for the synthesis of sugar acrylate/acrylamide hybrids and their utility" @default.
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- W2056321837 doi "https://doi.org/10.1016/j.carres.2011.04.018" @default.
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