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- W2056325475 abstract "Die thermische 1.5-Wasserstoffverschiebung des cis-1.1-Dideutero-pentadiens-(1.3) (3) wurde bei 185–205° kinetisch verfolgt und eine intramolekulare, nichtkatalysierte Reaktion erster Ordnung mit Aktivierungsparametern von ΔH≠ = 35.4 kcal/Mol und ΔS≠ = −7.1 cal/Grad · Mol sichergestellt. Durch Vergleich mit den kinetischen Daten der analogen 1.5-Deuteriumverschiebung ergibt sich ein kinetischer Isotopeneffekt von kH/kD = 1.15 · exp[1400/RT], der mit einem symmetrischen Übergangszustand der Reaktion im Einklang steht." @default.
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- W2056325475 date "1966-12-22" @default.
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- W2056325475 title "Wasserstoffverschiebungen, IV. Kinetischer Isotopeneffekt der 1.5-Wasserstoffverschiebung imcis-Pentadien-(1.3)" @default.
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- W2056325475 doi "https://doi.org/10.1002/jlac.19666990103" @default.
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