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- W2056350096 abstract "Two new copper complexes with triethanolamine (H3L) have been prepared using copper powder and characterized by X-ray crystallography, IR and EPR spectroscopy. These are [CuI(H3L)Cl]x⋅[CuII(H2L)Cl]1−x (X=0; 2/3) (1) and [CuII(H2L)SCN] (2). Both complexes are neutral species and contain copper atoms in trigonal bipyramidal environments. The important dimensions in 1 are Cu-N 2.011(5), 3Cu-O 2.073(3), Cu-Cl 2.239(2) Å and N-Cu-Cl=180.0°; in 2 Cu-NNCS 1.918(3), Cu-NH2Tea 1.983(3), Cu-O 2.004(2), 2Cu-O 2.13(1) Å and NH2Tea-Cu-NNCS=174.6(1)°. 2 has all the copper atoms in the oxidation state II, while the three-fold symmetry in 1 would suggest that the metal atoms are formally in the oxidation state I. Results of magnetic measurements of several samples of 1 are rationalized by assuming that a continuous range of composition for [CuI(H3L)Cl]x⋅[CuII(H2L)Cl]1−x can occur. In the case of x=0, 1 becomes a polymorph of the reported compound [CuII(H2L)Cl]." @default.
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- W2056350096 date "2001-06-01" @default.
- W2056350096 modified "2023-09-26" @default.
- W2056350096 title "Triethanolamine copper chloride prepared from zerovalent metal: another polymorph of a known Cu(II) compound or a mixed-valence complex with all-trigonal bipyramidal copper?" @default.
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- W2056350096 doi "https://doi.org/10.1016/s1463-0184(01)00010-7" @default.
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