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• W2056351602 abstract "Triflation of N3-protected uridines (NCOPh, NCHCHCOOMe, NNO2) has been investigates. A stable 2′-O-triflyl derivative, that of N-nitro-3′,5′-O-(tetraisopropyldisiloxane-1,3-diyl)uridine, has been isolated for the first time; by contrast to its congeners, it does not give cyclonicleoside-like intermediates. Nucleophilic attacks on this substrate lead to 2′ß-substituted nucleosides rather than the usual 2′α epimers. 3′-O-Triflyl N-nitro derivatives behave similarly. Several novel nucleosides (lyxo dihalo derivatives, 2′,3′-α-epoxy derivatives) are accessible by means of this approach." @default.
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• W2056351602 date "1998-10-01" @default.
• W2056351602 modified "2023-10-17" @default.
• W2056351602 title "Stabilisation of pyrimidine nucleoside triflates by N-nitro groups" @default.
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• W2056351602 doi "https://doi.org/10.1016/s0040-4039(98)01616-5" @default.
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