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- W2056381273 abstract "Diruthenium complexes (X)(dppe)2Ru−C≡C−1,4-C6H4−CH═CH−RuCl(CO)(PiPr3)2 (X = Cl, 1a; X = C≡CPh, 1b) containing an unsymmetrical (ethynyl)(vinyl)phenylene bridging ligand are compared to their symmetrical 1,4-bis(ethynyl)phenylene- and 1,4-divinylphenylene-bridged congeners and their mononuclear alkynyl precursors. Electrochemical and UV/vis/NIR, IR, and EPR spectroscopic studies on the neutral complexes and their various oxidized forms indicate bridging ligand-centered oxidation processes and uniform charge and spin delocalization over both dislike organoruthenium moieties despite differences in their intrinsic redox potentials. Comparison between the chloro and the phenylacetylide-terminated derivatives 1a,b suggests further that the conjugated organometallic π-system extends over the entire unsaturated backbone including the terminal ligand at the alkynyl ruthenium site. This paves the way to even more extended π-conjugated organoruthenium arrays for long-range electronic interactions." @default.
- W2056381273 created "2016-06-24" @default.
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- W2056381273 date "2010-10-15" @default.
- W2056381273 modified "2023-10-18" @default.
- W2056381273 title "Fully Delocalized (Ethynyl)(vinyl)phenylene-Bridged Diruthenium Radical Complexes" @default.
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- W2056381273 doi "https://doi.org/10.1021/om1007133" @default.
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