FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2056394967> ?p ?o ?g. }

• W2056394967 endingPage "6373" @default.
• W2056394967 startingPage "6373" @default.
• W2056394967 abstract "A new calix[6]crypturea (3) has been efficiently synthesized through a domino Staudinger/aza-Wittig reaction followed by a [1 + 1] macrocyclization step. In comparison to the previously reported tren-based calix[6]crypturea, this heteroditopic receptor 3 displays a more flexible and larger tris-ureido cap. Due to this structural alteration, 3 exhibits unique host–guest properties: (i) the protonation of its basic cap leads to a rigidification of the whole structure and, thus, allosteric control of the binding properties and selective guest switching processes are possible, (ii) its versatility is unprecedented in the literature since it can bind either neutral molecules, anions, primary/secondary ammonium ions, quaternary ammonium ions or contact ion pairs according to different modes of recognition and with a remarkable selectivity within each family of guest, (iii) cascade complexes even stable in a protic environment can be obtained. These remarkable features are nicely illustrated by the fact that, according to the nature of its counterion, an ammonium ion R1R2NH2+ can be accommodated into the cavity either as an independent guest, as a contact ion-pair or as a cascade complex. All these results are reminiscent of biological receptors and validate the strategy that consists of designing receptors presenting a high flexibility that can be controlled by an external stimulus." @default.
• W2056394967 created "2016-06-24" @default.
• W2056394967 creator A5003383965 @default.
• W2056394967 creator A5004559759 @default.
• W2056394967 creator A5059471132 @default.
• W2056394967 creator A5063705609 @default.
• W2056394967 date "2011-01-01" @default.
• W2056394967 modified "2023-09-25" @default.
• W2056394967 title "Acid–base modulation of a versatile heteroditopic calix[6]arene based receptor" @default.
• W2056394967 cites W1971160963 @default.
• W2056394967 cites W1972482061 @default.
• W2056394967 cites W1975295824 @default.
• W2056394967 cites W1976522198 @default.
• W2056394967 cites W1978826400 @default.
• W2056394967 cites W1980859462 @default.
• W2056394967 cites W1981038677 @default.
• W2056394967 cites W1984142980 @default.
• W2056394967 cites W1986356507 @default.
• W2056394967 cites W1986695228 @default.
• W2056394967 cites W1988197265 @default.
• W2056394967 cites W1988636074 @default.
• W2056394967 cites W1988924496 @default.
• W2056394967 cites W1991156792 @default.
• W2056394967 cites W1995040533 @default.
• W2056394967 cites W1998014003 @default.
• W2056394967 cites W2009046603 @default.
• W2056394967 cites W2012194915 @default.
• W2056394967 cites W2012339463 @default.
• W2056394967 cites W2012456693 @default.
• W2056394967 cites W2012859470 @default.
• W2056394967 cites W2015176883 @default.
• W2056394967 cites W2018726572 @default.
• W2056394967 cites W2019314140 @default.
• W2056394967 cites W2029904934 @default.
• W2056394967 cites W2032271223 @default.
• W2056394967 cites W2037155568 @default.
• W2056394967 cites W2037230021 @default.
• W2056394967 cites W2052348494 @default.
• W2056394967 cites W2053967698 @default.
• W2056394967 cites W2062942464 @default.
• W2056394967 cites W2064540273 @default.
• W2056394967 cites W2076915843 @default.
• W2056394967 cites W2079254281 @default.
• W2056394967 cites W2079638001 @default.
• W2056394967 cites W2086781270 @default.
• W2056394967 cites W2087313537 @default.
• W2056394967 cites W2093894980 @default.
• W2056394967 cites W2094418422 @default.
• W2056394967 cites W2103680519 @default.
• W2056394967 cites W2109834426 @default.
• W2056394967 cites W2127451058 @default.
• W2056394967 cites W2127884243 @default.
• W2056394967 cites W2128335519 @default.
• W2056394967 cites W2129425089 @default.
• W2056394967 cites W2133228783 @default.
• W2056394967 cites W2137444962 @default.
• W2056394967 cites W2139087639 @default.
• W2056394967 cites W2139618107 @default.
• W2056394967 cites W2151568097 @default.
• W2056394967 cites W2155144019 @default.
• W2056394967 cites W2155457524 @default.
• W2056394967 cites W2165565118 @default.
• W2056394967 cites W2166344590 @default.
• W2056394967 cites W2167803957 @default.
• W2056394967 cites W2174480528 @default.
• W2056394967 cites W2477216873 @default.
• W2056394967 cites W2952179347 @default.
• W2056394967 cites W4210979639 @default.
• W2056394967 cites W4231935621 @default.
• W2056394967 doi "https://doi.org/10.1039/c1ob05759f" @default.
• W2056394967 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21814689" @default.
• W2056394967 hasPublicationYear "2011" @default.
• W2056394967 type Work @default.
• W2056394967 sameAs 2056394967 @default.
• W2056394967 citedByCount "24" @default.
• W2056394967 countsByYear W20563949672012 @default.
• W2056394967 countsByYear W20563949672013 @default.
• W2056394967 countsByYear W20563949672014 @default.
• W2056394967 countsByYear W20563949672015 @default.
• W2056394967 countsByYear W20563949672016 @default.
• W2056394967 countsByYear W20563949672017 @default.
• W2056394967 countsByYear W20563949672018 @default.
• W2056394967 countsByYear W20563949672019 @default.
• W2056394967 countsByYear W20563949672023 @default.
• W2056394967 crossrefType "journal-article" @default.
• W2056394967 hasAuthorship W2056394967A5003383965 @default.
• W2056394967 hasAuthorship W2056394967A5004559759 @default.
• W2056394967 hasAuthorship W2056394967A5059471132 @default.
• W2056394967 hasAuthorship W2056394967A5063705609 @default.
• W2056394967 hasConcept C118792377 @default.
• W2056394967 hasConcept C145148216 @default.
• W2056394967 hasConcept C161790260 @default.
• W2056394967 hasConcept C170493617 @default.
• W2056394967 hasConcept C178790620 @default.
• W2056394967 hasConcept C185592680 @default.
• W2056394967 hasConcept C21951064 @default.
• W2056394967 hasConcept C2779870022 @default.
• W2056394967 hasConcept C30095370 @default.

• next