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- W2056405412 abstract "The first total synthesis for the (+)-hyacinthacine A3 1 in a highly stereocontrolled manner, is reported herein. An appropriately protected polyhydroxylated pyrrolidine, such as (2R,3R,4R,5R)-3,4-dibenzyloxy-N-tert-butyloxycarbonyl-2′-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine 2, (DMDP protected), readily available from d-fructose, was chosen as the homochiral starting material. The absolute configuration of natural 1 is also unambiguously established." @default.
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- W2056405412 date "2002-08-01" @default.
- W2056405412 modified "2023-10-15" @default.
- W2056405412 title "Polyhydroxylated pyrrolizidines. Part 2: The first total synthesis of (+)-hyacinthacine A3" @default.
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- W2056405412 doi "https://doi.org/10.1016/s0957-4166(02)00408-1" @default.
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