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- W2056451713 abstract "A super high-throughput screening (SHTS) system can be constructed by combining high-performance liquid chromatography (HPLC), optical rotation (OR), and refractive index unit (RIU) to determine not only the enantioselectivity of the addition of diethylzinc to an aliphatic aldehyde catalyzed by a binaphthol-zinc complex through asymmetric activation with chiral Schiff bases, but also the enantiopurity of a carbohydrate. The enantiomeric (e) factor, which we define here as optical rotation per refractive index unit, is linearly related to the percent enantiomeric excess (%ee) and is independent of concentration." @default.
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- W2056451713 date "2000-01-01" @default.
- W2056451713 modified "2023-10-16" @default.
- W2056451713 title "Optical rotation per refractive index unit, or enantiomeric (e) factor, for screening enantioselective catalysts through asymmetric activation or carbohydrates" @default.
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- W2056451713 doi "https://doi.org/10.1002/(sici)1520-636x(2000)12:5/6<544::aid-chir43>3.0.co;2-a" @default.
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