FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2056454502> ?p ?o ?g. }

• W2056454502 endingPage "668" @default.
• W2056454502 startingPage "654" @default.
• W2056454502 abstract "The present investigation is a rather substantial extension and elaboration of our previous work on the same reaction. In this article we accomplish four primary objectives: 1. We show quantitatively how sensitive the high-temperature rate coefficient k(T) is to E02, the threshold energy of the transition state for direct molecular elimination of HO2 from ethylperoxy radical (C2H5O2), thus deducing a value of E02=−3.0 kcal/mol (measured from reactants). 2. We derive the result that k0(T) ≈ k′∞(T) in the high-temperature regime, where k0(T) is the zero-pressure rate coefficient, and k′∞(T) is the infinite-pressure rate coefficient for the bimolecular channel. 3. Most importantly, we discuss the three different regimes of the reaction (low-temperature, transition, and high-temperature) in terms of the eigenvectors and eigenvalues of G, the transition matrix of the master equation. The transition regime is shown to be a region of avoided crossing between the two chemically significant eigenvalue curves in which the thermal rate coefficient k (T ,p) jumps from one eigenvalue to the other. This jump is accompanied by a “mixing” of the corresponding eigenvectors, through which both eigenvectors deplete the reactant. The onset of the high-temperature regime is triggered by reaching the “stabilization limit” of the ethylperoxy adduct, a limit that is induced by a shift in equilibrium of the stabilization reaction. Our identification of the prompt and secondary HO2 formed by the reaction with these eigenvalue/eigenvector pairs leads to good agreement between theory and the experiments of Clifford et al. (J Phys Chem A 2000, 104, 11549–11560). 4. Lastly, we describe the master equation results in terms of a set of elementary reactions and phenomenological rate coefficients. © 2001 John Wiley & Sons, Inc. Int J Chem Kinet 33: 732–740, 2001" @default.
• W2056454502 created "2016-06-24" @default.
• W2056454502 creator A5046704046 @default.
• W2056454502 creator A5060098801 @default.
• W2056454502 date "2001-09-21" @default.
• W2056454502 modified "2023-10-01" @default.
• W2056454502 title "The reaction between ethyl and molecular oxygen II: Further analysis" @default.
• W2056454502 cites W116383179 @default.
• W2056454502 cites W128360279 @default.
• W2056454502 cites W1492476004 @default.
• W2056454502 cites W1580910667 @default.
• W2056454502 cites W1630108054 @default.
• W2056454502 cites W1966428804 @default.
• W2056454502 cites W1966685711 @default.
• W2056454502 cites W1969823101 @default.
• W2056454502 cites W1973338259 @default.
• W2056454502 cites W1988557394 @default.
• W2056454502 cites W1988942888 @default.
• W2056454502 cites W1989662956 @default.
• W2056454502 cites W1992239811 @default.
• W2056454502 cites W2029549258 @default.
• W2056454502 cites W2046132542 @default.
• W2056454502 cites W2053320967 @default.
• W2056454502 cites W2053883537 @default.
• W2056454502 cites W2055540153 @default.
• W2056454502 cites W2062357655 @default.
• W2056454502 cites W2063462567 @default.
• W2056454502 cites W2064308942 @default.
• W2056454502 cites W2067166752 @default.
• W2056454502 cites W2067866670 @default.
• W2056454502 cites W2068895178 @default.
• W2056454502 cites W2075723525 @default.
• W2056454502 cites W2108158537 @default.
• W2056454502 cites W2232947517 @default.
• W2056454502 cites W2319839200 @default.
• W2056454502 cites W2493165199 @default.
• W2056454502 cites W318194513 @default.
• W2056454502 cites W4233517376 @default.
• W2056454502 cites W81990881 @default.
• W2056454502 cites W95991938 @default.
• W2056454502 doi "https://doi.org/10.1002/kin.1063" @default.
• W2056454502 hasPublicationYear "2001" @default.
• W2056454502 type Work @default.
• W2056454502 sameAs 2056454502 @default.
• W2056454502 citedByCount "118" @default.
• W2056454502 countsByYear W20564545022013 @default.
• W2056454502 countsByYear W20564545022014 @default.
• W2056454502 countsByYear W20564545022015 @default.
• W2056454502 countsByYear W20564545022016 @default.
• W2056454502 countsByYear W20564545022017 @default.
• W2056454502 countsByYear W20564545022018 @default.
• W2056454502 countsByYear W20564545022019 @default.
• W2056454502 countsByYear W20564545022020 @default.
• W2056454502 countsByYear W20564545022021 @default.
• W2056454502 countsByYear W20564545022022 @default.
• W2056454502 countsByYear W20564545022023 @default.
• W2056454502 crossrefType "journal-article" @default.
• W2056454502 hasAuthorship W2056454502A5046704046 @default.
• W2056454502 hasAuthorship W2056454502A5060098801 @default.
• W2056454502 hasConcept C106487976 @default.
• W2056454502 hasConcept C108204754 @default.
• W2056454502 hasConcept C121332964 @default.
• W2056454502 hasConcept C128805008 @default.
• W2056454502 hasConcept C158693339 @default.
• W2056454502 hasConcept C16643434 @default.
• W2056454502 hasConcept C178790620 @default.
• W2056454502 hasConcept C185592680 @default.
• W2056454502 hasConcept C18762648 @default.
• W2056454502 hasConcept C43617362 @default.
• W2056454502 hasConcept C62520636 @default.
• W2056454502 hasConcept C84114770 @default.
• W2056454502 hasConcept C97355855 @default.
• W2056454502 hasConceptScore W2056454502C106487976 @default.
• W2056454502 hasConceptScore W2056454502C108204754 @default.
• W2056454502 hasConceptScore W2056454502C121332964 @default.
• W2056454502 hasConceptScore W2056454502C128805008 @default.
• W2056454502 hasConceptScore W2056454502C158693339 @default.
• W2056454502 hasConceptScore W2056454502C16643434 @default.
• W2056454502 hasConceptScore W2056454502C178790620 @default.
• W2056454502 hasConceptScore W2056454502C185592680 @default.
• W2056454502 hasConceptScore W2056454502C18762648 @default.
• W2056454502 hasConceptScore W2056454502C43617362 @default.
• W2056454502 hasConceptScore W2056454502C62520636 @default.
• W2056454502 hasConceptScore W2056454502C84114770 @default.
• W2056454502 hasConceptScore W2056454502C97355855 @default.
• W2056454502 hasIssue "11" @default.
• W2056454502 hasLocation W20564545021 @default.
• W2056454502 hasOpenAccess W2056454502 @default.
• W2056454502 hasPrimaryLocation W20564545021 @default.
• W2056454502 hasRelatedWork W1991616557 @default.
• W2056454502 hasRelatedWork W2016472295 @default.
• W2056454502 hasRelatedWork W2026948689 @default.
• W2056454502 hasRelatedWork W2047991101 @default.
• W2056454502 hasRelatedWork W2334792521 @default.
• W2056454502 hasRelatedWork W2341880960 @default.
• W2056454502 hasRelatedWork W2951300725 @default.
• W2056454502 hasRelatedWork W2951566524 @default.
• W2056454502 hasRelatedWork W2953125259 @default.

• next