Matches in SemOpenAlex for { <https://semopenalex.org/work/W2056456070> ?p ?o ?g. }
- W2056456070 endingPage "84" @default.
- W2056456070 startingPage "75" @default.
- W2056456070 abstract "Silica-supported Pd and PdZn nanoparticles of a similar size were evaluated for neopentane hydrogenolysis/isomerization and propane hydrogenolysis/dehydrogenation. Monometallic Pd showed high neopentane hydrogenolysis selectivity. Addition of small amounts of Zn to Pd lead Pd–Zn scatters in the EXAFS spectrum and an increase in the linear bonded CO by IR. In addition, the neopentane turnover rate decreased by nearly 10 times with little change in the selectivity. Increasing amounts of Zn lead to greater Pd–Zn interactions, higher linear-to-bridging CO ratios by IR and complete loss of neopentane conversion. Pd NPs also had high selectivity for propane hydrogenolysis and thus were poorly selective for propylene. The PdZn bimetallic catalysts, however, were able to preferentially catalyze dehydrogenation, were not active for propane hydrogenolysis, and thus were highly selective for propylene formation. The decrease in hydrogenolysis selectivity was attributed to the isolation of active Pd atoms by inactive metallic Zn, demonstrating that hydrogenolysis requires a particular reactive ensemble whereas propane dehydrogenation does not." @default.
- W2056456070 created "2016-06-24" @default.
- W2056456070 creator A5012765213 @default.
- W2056456070 creator A5015614870 @default.
- W2056456070 creator A5019171835 @default.
- W2056456070 creator A5023735477 @default.
- W2056456070 creator A5053714805 @default.
- W2056456070 creator A5072548261 @default.
- W2056456070 date "2014-10-01" @default.
- W2056456070 modified "2023-10-18" @default.
- W2056456070 title "Modifying structure-sensitive reactions by addition of Zn to Pd" @default.
- W2056456070 cites W1967843311 @default.
- W2056456070 cites W1968579219 @default.
- W2056456070 cites W1975632246 @default.
- W2056456070 cites W1976659143 @default.
- W2056456070 cites W1978459804 @default.
- W2056456070 cites W1978491150 @default.
- W2056456070 cites W1979575395 @default.
- W2056456070 cites W1981635493 @default.
- W2056456070 cites W1982263343 @default.
- W2056456070 cites W1985947461 @default.
- W2056456070 cites W1987823946 @default.
- W2056456070 cites W1987963404 @default.
- W2056456070 cites W1994156797 @default.
- W2056456070 cites W1997068089 @default.
- W2056456070 cites W2000641102 @default.
- W2056456070 cites W2005519535 @default.
- W2056456070 cites W2010565833 @default.
- W2056456070 cites W2011558429 @default.
- W2056456070 cites W2041862837 @default.
- W2056456070 cites W2047204152 @default.
- W2056456070 cites W2048570590 @default.
- W2056456070 cites W2048894172 @default.
- W2056456070 cites W2048946470 @default.
- W2056456070 cites W2050822244 @default.
- W2056456070 cites W2054254706 @default.
- W2056456070 cites W2060353580 @default.
- W2056456070 cites W2062867233 @default.
- W2056456070 cites W2066058117 @default.
- W2056456070 cites W2071392543 @default.
- W2056456070 cites W2074599973 @default.
- W2056456070 cites W2077616641 @default.
- W2056456070 cites W2077740555 @default.
- W2056456070 cites W2081564785 @default.
- W2056456070 cites W2081720837 @default.
- W2056456070 cites W2088104975 @default.
- W2056456070 cites W2090433711 @default.
- W2056456070 cites W2090443936 @default.
- W2056456070 cites W2091510526 @default.
- W2056456070 cites W2092700057 @default.
- W2056456070 cites W2107875376 @default.
- W2056456070 cites W2117960031 @default.
- W2056456070 cites W2126277733 @default.
- W2056456070 cites W2136731663 @default.
- W2056456070 cites W2142220501 @default.
- W2056456070 cites W2143399209 @default.
- W2056456070 cites W2160758247 @default.
- W2056456070 cites W2171373893 @default.
- W2056456070 cites W2172006907 @default.
- W2056456070 cites W2316480048 @default.
- W2056456070 cites W2323445579 @default.
- W2056456070 cites W2327480778 @default.
- W2056456070 cites W2331370730 @default.
- W2056456070 cites W2331505952 @default.
- W2056456070 cites W2335334080 @default.
- W2056456070 cites W2951306555 @default.
- W2056456070 doi "https://doi.org/10.1016/j.jcat.2014.07.016" @default.
- W2056456070 hasPublicationYear "2014" @default.
- W2056456070 type Work @default.
- W2056456070 sameAs 2056456070 @default.
- W2056456070 citedByCount "74" @default.
- W2056456070 countsByYear W20564560702015 @default.
- W2056456070 countsByYear W20564560702016 @default.
- W2056456070 countsByYear W20564560702017 @default.
- W2056456070 countsByYear W20564560702018 @default.
- W2056456070 countsByYear W20564560702019 @default.
- W2056456070 countsByYear W20564560702020 @default.
- W2056456070 countsByYear W20564560702021 @default.
- W2056456070 countsByYear W20564560702022 @default.
- W2056456070 countsByYear W20564560702023 @default.
- W2056456070 crossrefType "journal-article" @default.
- W2056456070 hasAuthorship W2056456070A5012765213 @default.
- W2056456070 hasAuthorship W2056456070A5015614870 @default.
- W2056456070 hasAuthorship W2056456070A5019171835 @default.
- W2056456070 hasAuthorship W2056456070A5023735477 @default.
- W2056456070 hasAuthorship W2056456070A5053714805 @default.
- W2056456070 hasAuthorship W2056456070A5072548261 @default.
- W2056456070 hasBestOaLocation W20564560701 @default.
- W2056456070 hasConcept C118792377 @default.
- W2056456070 hasConcept C119889771 @default.
- W2056456070 hasConcept C161790260 @default.
- W2056456070 hasConcept C178790620 @default.
- W2056456070 hasConcept C179104552 @default.
- W2056456070 hasConcept C181886296 @default.
- W2056456070 hasConcept C185592680 @default.
- W2056456070 hasConcept C2776345496 @default.
- W2056456070 hasConcept C2777954637 @default.
- W2056456070 hasConcept C2779211955 @default.