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- W2056469433 abstract "Abstract The stability of metal ion - polyether complexes for cyclic polyethers is greater than their linear analogs. This effect has been referred to as the macrocyclic effect. Here, we report a “mechanistic” macrocyclic effect observed in low pressure gas phase ion-molecule reactions involving transition metal ions and both linear and crown ethers. The crown ethers are much more reactive with Cr+ and Fe+ than their linear analog. Presumably, the cyclic ligand forces more parts of the molecule to interact with the metal ion, while only one part of the linear polyethers reacts with these metal centers." @default.
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- W2056469433 date "1983-03-01" @default.
- W2056469433 modified "2023-09-27" @default.
- W2056469433 title "A “Mechanistic” Macrocyclic Effect in the Gas Phase Chemistry of Metal Ions with Polyethers" @default.
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- W2056469433 doi "https://doi.org/10.1080/00387018308062337" @default.
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