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• W2056500782 abstract "Abstract: The carbonyl stress that leads to the formation of advanced glycation end products (AGEs) has drawn much attention recently because of its micro‐ and macrovascular implications. During monitoring of methylglyoxal (MG), the efficiency of phenolics to directly trap MG can be demonstrated. Twenty compounds consisting of a single benzene ring structure with the addition of at least one hydroxyl group were allowed to react with MG at 37 °C for 1 h under physiological conditions in pH 7.4 phosphate buffer solution. Compounds composed of a benzene structure with a mono‐hydroxyl substitute cannot react with MG. Among benzenediols and di‐hydroxyl benzoic acids, only hydroquinone reacted with MG and showed a 13% decrease in MG. Nevertheless, high reactivity was shown for 3 benzenetriols. The percentages of MG remaining were 45%, 51%, and 36% for pyrogallol, 1,2,4‐trihydroxybenzene, and 1,3,5‐trihydroxybenzene, respectively. When a carboxyl group is added to the benzenetriols, steric hindrance and carbon electron charges on benzene ring are the influential factors in reactivity. Using computational chemistry calculations, a carbon electron charge of −0.24 was the minimum value for high reactivity." @default.
• W2056500782 created "2016-06-24" @default.
• W2056500782 creator A5014591434 @default.
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• W2056500782 date "2011-03-16" @default.
• W2056500782 modified "2023-10-17" @default.
• W2056500782 title "Efficiency of Trapping Methylglyoxal by Phenols and Phenolic Acids" @default.
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• W2056500782 doi "https://doi.org/10.1111/j.1750-3841.2011.02067.x" @default.
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• W2056500782 hasPublicationYear "2011" @default.
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