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- W2056513901 abstract "Abstract Cyclocopolymerizations of 5,6-benzo-l,2:9,10-diepoxy-4,7-dioxa-deca-5-ene (BDD) and monoepoxy comonomers, propylene oxide (PO), epichlorohydrin (ECH), and phenyl glycidyl ether (PGE), were carried out with SnCl4 to form gel-free copolymers with no residual epoxy groups. The copolymerization parameters were r, = 1.09 and r2 = 0.86 for BDD (M1)-PGE (M2). In addition, 5, 6:14,15-dibenzo-l,2:18,19-diepoxy-4,7,-10,13,16-pentaoxanonadeca-5,14-diene (DDP) with PO, ECH, or PGE were copolymerized with SnCl4 in CH2C12 and with KOH in DMSO to form copolymers with dibenzo-19-crown-6 units. Poly[(dibenzo-19-crown-6)-co-PO] and poly[(dibenzo-19-crown-6)-co-PGE] showed lower extracting yields for alkali-metal picrates than did the homopolymer of DDP, poly(dibenzo-19-crown-6). However, poly[(dibenzo-19-crown-6)-co-PGE] exhibited a higher selectivity for K+ than did the other polymers." @default.
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- W2056513901 date "1994-06-01" @default.
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- W2056513901 title "Cyclopolymerization of α,Ω-Diepoxide with Monoepoxy Comonomer. Synthesis and Cation-Binding Property of Copolymers with Dibenzo-19-Crown-6 Units" @default.
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- W2056513901 doi "https://doi.org/10.1080/10601329409349753" @default.
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