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- W2056514583 abstract "Radiation-induced oxidation of cysteine in an acid medium was studied by measuring the hydrogen yields at an initiation stage of radiolysis. In the deaerated system G(H2)=4.0 along with the G(–CySH)=7.1 were observed and the results can be interpreted in terms of the yields of primary radicals from the radiolysis of water in 0.8 N sulfuric acid medium. From stoichio-metric view point it is predicted that the radiolysis takes place through cysteine radical as intermediate to form cystine. In the aerated system on the other hand, the radiolysis of cysteine is much complicated. For a possible explanation satisfying all the G values obtained, 10.5 in the disappearance of cysteine, 4.0 in the formation of hydrogen peroxide and 0.4 in the hydrogen, the air oxidation of cysteine caused by the radicals, HO2 and OH which produce H2O2 and O2 by the radical recombination, is proposed as mechanism. The radiolysis of cysteine is greatly reduced by complexation with metallic ion as biscysteinatocobaltate(III) complex. ..." @default.
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- W2056514583 date "1968-04-01" @default.
- W2056514583 modified "2023-10-16" @default.
- W2056514583 title "The Hydrogen Yields in the Radiolysis of Cysteine and Biscysteinatocobaltate(III) in 0.8 N Sulfuric Acid" @default.
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- W2056514583 doi "https://doi.org/10.1246/bcsj.41.888" @default.
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