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- W2056516342 abstract "Control of nanostructure formation by a diblock-type supramacromolecule via biocomplementary hydrogen bonding has been achieved. Two different homopolymers, poly(4-trimethylsilylstyrene) and poly(styrene-d8), that are end-decorated with complementary oligonucleotides, i.e., thymidine phosphates and deoxyadenosine phosphates, were prepared by using the phosphoramidite method and blended successively. Association behavior in a blend solution was examined with NMR, and a cast bulk film obtained from the solution has been confirmed to show a nanophase-separated structure by transmission electron microscopy and X-ray scattering. Suppression of this nanostructure formation of a block-type supramacromolecule was also attained by adding a smaller agent as an inhibitor." @default.
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- W2056516342 date "2006-04-29" @default.
- W2056516342 modified "2023-09-27" @default.
- W2056516342 title "Diblock-Type Supramacromolecule via Biocomplementary Hydrogen Bonding" @default.
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- W2056516342 doi "https://doi.org/10.1021/bm0602280" @default.
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