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• W2056517666 abstract "The reactions of 1-{[2-(arylazo)phenyl]iminomethyl}-2-naphthol, H2Lnap [where H represents the dissociable proton upon complexation and aryl groups of H2Lnap are phenyl for H2L1nap; p-methyl phenyl for H2L2nap and p-chloro phenyl for H2L3nap] with nickel acetate tetra hydrate or disodium tetrachloropalladate in methanol afforded M–C(aryl) bonded species of composition [M(Lnap)] (M = Ni(II) and Pd (II)). The dinegative (Lnap)2− ligands bind the Ni(II) or Pd(II) in tetradentate (C, N, N, O) fashion in distorted square planar geometry. Ligands and complexes were characterized by spectroscopic methods. The X-ray structures of H2L1nap, [Ni(L1nap)] and [Pd(L1nap)] were determined to authenticate the characterization. Reactions with metachloroperbenzoic acid (mCPBA), TBHP and hydrogen peroxide leading to oxygen insertion into the M-C bond have been examined. Luminescent properties of ligands and complexes have been reported." @default.
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• W2056517666 date "2013-03-01" @default.
• W2056517666 modified "2023-09-24" @default.
• W2056517666 title "Activation of ortho C–H bond by nickel(II) acetate or sodium tetrachloropalladate(II) in naphthyl imino derivatives of azobenzene" @default.
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• W2056517666 doi "https://doi.org/10.1016/j.poly.2012.12.011" @default.
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