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- W2056519452 abstract "A number of catlonic hydrldo complexes of transitmn metals, stabilized by tertiary phosphmes, have been described in the last few years Among the metals of the nickel and of the cobalt group, many very stable derlvatlves of platmtim’-6 and lr~dmm7-*0, but only a few of palladmm” , nickel’*, rhodmm13 and cobalt I4 are known Among the metals of the iron group, only a series of catlonlc hydrldo complexes of general formula trans-[MH(L)(depe)2]BPh4 (M = Fe, Ru, OS, L = CO, p-Me0 C6H4 NC, N,, PhCN, depe = Et2P CH2 CH, PEt,) has been described”” We have now prepared a new, very stable catlomc hydrldo complex of formula [FeH(dppe)* ] Y (dppe = Ph, P-CH, CH, PPh2 , Y = BPh,, C104) This coordmatlvely unsaturated complex of Iron (II) reacts very easily with a number of neutral hgands to gve a new series of catromc hydrldo complexes of general formula trarzs-[FeH(L)(dppe),]Y (L = Me2 CO, N2, CO, NHs, Py, MeCN, PhCN), with H2 to gve the new catlomc hydrldo complex of iron [FeH3(dppe)2] Y, and with CO*, CS2, O2 and olefins to @ve compounds wluch have not yet been fully characterized The pentacoordmated catromc hydrldo complex of iron(H) has been obtained both by exchange under argon from FeHCl(dppe), (ref 16) according to the reaction" @default.
- W2056519452 created "2016-06-24" @default.
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- W2056519452 date "1972-07-01" @default.
- W2056519452 modified "2023-10-17" @default.
- W2056519452 title "New cationic hydrido and hydrido-dinitrogen complexes of iron" @default.
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- W2056519452 doi "https://doi.org/10.1016/s0010-8545(00)80054-5" @default.
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