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- W2056521444 abstract "Ni(II) and Co(II) coordination with the macrocyclic ligand 1,4-dioxa-7,10,13-triazacyclopentadecane (L) has been investigated in solution (Co(II) and Ni(II)) and in the solid state (Ni(II)). Complexation equilibria have been studied by means of potentiometric titrations in 0.15 mol dm-3 NaCl, at 298.1 ± 0.1 K, evidencing the formation of [ML]2+, [MLOH]+, and [ML(OH)2] (M = Co, Ni) species. Under aerobic conditions, the mononuclear Co(II) complex binds dioxygen, forming the dibridged [Co2L2(O2)OH]3+. This is the unique oxygenated species formed. The importance of the bridging OH- anion for the formation of the oxygenated complex has been evidenced by competitive coordination of SCN-. Structural information has been obtained by resolving the crystal structure of the [NiLCl][NiL(H2O)](ClO4)3 compound. The structure contains [NiLCl]+ and [NiL(H2O)]2+ cations in which the metal ions have octahedral coordination environments determined by five ligand donor atoms and one Cl-/H2O." @default.
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- W2056521444 date "2000-10-01" @default.
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- W2056521444 title "Complexation of Ni(II) and Co(II) with 1,4-Dioxa-7,10,13-triazacyclopentadecane (<b>L</b>). Crystal Structure of [NiLCl][NiL(H<sub>2</sub>O)](ClO<sub>4</sub>)<sub>3</sub> and Macrocycle-Induced Dioxygen Binding" @default.
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- W2056521444 doi "https://doi.org/10.1021/ie000095d" @default.
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