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• W2056521791 endingPage "2847" @default.
• W2056521791 startingPage "2847" @default.
• W2056521791 abstract "The stereoselective synthesis of a C9–C19 fragment of the potent antitumor agent peloruside A is disclosed. The C11 stereogenic centre was created by a vinylogous Mukaiyama aldol reaction following Carreira's protocol, with excellent stereocontrol. The C13 stereogenic centre was introduced by a substrate controlled reduction. The C15 stereocentre was fashioned using Noyori's asymmetric transfer hydrogenation while the Z-trisubstituted double bond was formed by a regioselective hydrostannation of an alkyne followed by methylation of the resultant vinyl stannane using Lipshutz's protocol. The C18 chiral centre was introduced by a chemoenzymatic route." @default.
• W2056521791 created "2016-06-24" @default.
• W2056521791 creator A5031662314 @default.
• W2056521791 creator A5046995850 @default.
• W2056521791 date "2013-01-01" @default.
• W2056521791 modified "2023-10-09" @default.
• W2056521791 title "A stereoselective synthesis of the C9–C19 subunit of (+)-peloruside A" @default.
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• W2056521791 doi "https://doi.org/10.1039/c3ob27508f" @default.
• W2056521791 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23478973" @default.
• W2056521791 hasPublicationYear "2013" @default.
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