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- W2056524519 abstract "Abstract This paper reports the synthesis of new 4-phospho- d -erythronic acid derivatives, namely 4-phospho- d -erythronohydroxamic acid ( 1 ), 4-phospho- d -erythronohydrazide ( 2 ), and 4-phospho- d -erythronamide ( 3 ), and their kinetic evaluation as new competitive inhibitors of the isomerization reaction between d -ribose 5-phosphate and d -ribulose 5-phosphate catalyzed by spinach ribose-5-phosphate isomerase (RPI). By comparison to the only known RPI inhibitor, 4-phospho- d -erythronate ( 4 , K i =28 μM, K m / K i =270), the hydroxamic acid 1 , obtained by an eight-step synthesis from d -arabinose, appears as a new potent high-energy intermediate analogue inhibitor of the isomerization reaction ( K i =29 μM, K m / K i =260)." @default.
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- W2056524519 date "2004-01-01" @default.
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- W2056524519 title "Synthesis and evaluation of new 4-phospho-d-erythronic acid derivatives as competitive inhibitors of spinach ribose-5-phosphate isomerase" @default.
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- W2056524519 doi "https://doi.org/10.1016/j.tetlet.2003.11.038" @default.
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