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- W2056525012 abstract "Anwendungspotential für stöchiometrische und auch katalytische Reaktionen haben die Rhodium‐Phosphan‐Komplexe [{Ph 2 P(CH 2 ) n PPh 2 } 2 Rh][MgCl] 1 ( n = 2, 1a ; n = 3, 1b ), die aus den Chlorid‐Komplexen 2 durch Reaktion mit aktivem Magnesium zugänglich sind. Die „Grignard‐analogen”︁ Verbindungen 1 lassen sich durch Protolyse, Alkylierung und Silylierung zu den Verbindungen 3 (E = H, Me bzw. SiMe 3 ) umsetzen. Die gegenseitige Umwandlung der Komplexe 2a und 1a kann für einen katalytischen Zwei‐Elektronen‐Transfer von Magnesium auf CO 2 unter Bildung von CO und CO 3 2− genutzt werden. magnified image magnified image" @default.
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- W2056525012 date "1997-03-03" @default.
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- W2056525012 title "„Grignard‐analoge”︁ Rhodium‐Phosphan‐Komplexe" @default.
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- W2056525012 doi "https://doi.org/10.1002/ange.19971090515" @default.
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