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- W2056526618 abstract "Abstract The three isomeric 2-, 3- and 4-pivalamidoquinolines react with lithiating reagents to give their metalation or nucleophilic addition products. Metalation occurs best with the 2-substituted isomer. Suprisingly the 4-pivalamidoquinoline is lithiated at C(8). A new directing group derived from the amine, the ureido substituent, directs the lithiation at C(2) of the 3-aminoquinoline derivative." @default.
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- W2056526618 date "1988-10-01" @default.
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- W2056526618 title "Etude de la métallation des pivalamido-2, -3 et -4 quinoléines" @default.
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- W2056526618 doi "https://doi.org/10.1016/0022-328x(88)80652-1" @default.
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