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- W2056527660 abstract "Abstract Synthesis and characterization of gold‐nanoparticle‐cored dendrimers (NCDs), in which the dendrons are attached to the gold core through gold–carbon bonds, are described. Synthesis of these materials involved the simultaneous reduction of HAuCl 4 and a Fréchet‐type dendron with a diazonium group at the focal point, all in an organic solvent such as toluene. These materials possess a nanometer‐sized gold core surrounded by a shell of polyaryl ether dendrons, which are connected radially to the core. The NCDs were characterized by TEM, thermogravimetric analysis (TGA), and IR, UV, and NMR spectroscopic techniques. Average particle diameter of the NCDs ranged from 4.7 to 5.5 nm for the different generations. All NCDs exhibit the characteristic plasmon absorption of gold nanoparticles at 520 nm. Average numbers of dendrons per NCD in AuG n were calculated using results from TGA and TEM studies. Multiple layering of the dendrons is proposed as a possible reason for the high dendron/NCD value." @default.
- W2056527660 created "2016-06-24" @default.
- W2056527660 creator A5004233714 @default.
- W2056527660 creator A5086306652 @default.
- W2056527660 date "2010-03-30" @default.
- W2056527660 modified "2023-10-18" @default.
- W2056527660 title "Synthesis and Characterization of Gold-Nanoparticle-Cored Dendrimers Stabilized by Metal-Carbon Bonds" @default.
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- W2056527660 doi "https://doi.org/10.1002/asia.200900388" @default.
- W2056527660 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20183852" @default.
- W2056527660 hasPublicationYear "2010" @default.
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