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- W2056529739 abstract "Recent progress in the field of silver(I)-chalcogenide halides and silver(I)-polychalcogenide halides led to the discovery of a reasonable number of new phases, solid solutions and even a new substance class of materials with favorable electronic and thermoelectric properties. Most of these new compounds are characterized by a pronounced ion mobility, polymorphism, and complex structures, which result in severe problems during the structure solution, the refinement, and even the description of the crystal structures. Herein we report on a very simple but effective building principle and a topological structure approach, which are both based on the separate description of anion substructures and the introduction of discrete building blocks. Such a topological principle helps to understand the complex structural relations and allows one to discuss all known chalcogenide and polychalcogenide halides in a continuous sequence of compounds. Following this principle it is possible to understand physical properties and to predict new phases in the system." @default.
- W2056529739 created "2016-06-24" @default.
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- W2056529739 date "2010-03-23" @default.
- W2056529739 modified "2023-09-25" @default.
- W2056529739 title "ChemInform Abstract: Structure Topology in Silver(I)-(poly)chalcogenide Halides: A Helpful Tool to Understand Structure Relations and Properties." @default.
- W2056529739 cites W2950694610 @default.
- W2056529739 doi "https://doi.org/10.1002/chin.201012004" @default.
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