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• W2056531189 abstract "Quadrupole mass spectrometry of the neutral products accompanying irradiation of single crystal NaNO3 with a pulsed beam of 1–3 keV electrons shows intense NO and O2 emissions and smaller amounts of Na and NO2. Time-of-flight and intensity measurements as a function of pulse width and temperature are consistent with NO emission via a thermally assisted, electronic emission mechanism. The activation energy for the thermally assisted process is about 0.11 eV -similar to the excitation energies for internal vibrational modes of the NO3− anion. The emission of neutral O2 involves fairly complex reactions with dissociation products and is also thermally assisted at temperatures above 380 K. Mass-selected ion emission measurements indicate copious H+ emission, where the temperature dependence of the H+ intensity is similar to that of NO. We propose that H+ emission is limited by the density of appropriate surface defect sites, and that these sites are directly related to NO3− dissociation." @default.
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• W2056531189 date "1995-11-01" @default.
• W2056531189 modified "2023-09-27" @default.
• W2056531189 title "Electron stimulated neutral and ion emission from single crystal NaNO3" @default.
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• W2056531189 doi "https://doi.org/10.1016/0168-583x(95)00610-9" @default.
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