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- W2056531254 abstract "A series of P-benzyl functionalised dithieno[3,2-b:2′,3′-b]phospholes with different substitution pattern at the phosphorus as well as the conjugated scaffold was synthesised and characterised via optical spectroscopy. Single crystal X-ray crystallography was performed on one species. The experimentally observed data were solidified with density functional theory calculations. In contrast to related benzylated P-phenyl phospholium species, the new systems show pronounced photoluminescence in solution, with the exception of the phosphole sulfide species. The observed photophysics could be explained with dominating π→π* transitions, despite the presence of the benzyl group that had been found to quench the fluorescence in the predecessor benzyl system with P-phenyl substituent." @default.
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- W2056531254 date "2013-01-01" @default.
- W2056531254 modified "2023-09-24" @default.
- W2056531254 title "Luminescent P-Benzyl Dithienophospholes – A Joint Experimental and Theoretical Investigation" @default.
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- W2056531254 doi "https://doi.org/10.1071/ch13220" @default.
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