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• W2056533151 abstract "The compound Ru2Cl(μ-O2CC6H4-p-CMe3)4 has been prepared by the reaction of Ru2Cl(μ-O2CCH3)4 with p-tertbutylbenzoic acid in a water/methanol mixture (1 : 1). The reactions of Ru2Cl(μ-O2CC6H4-p-CMe3)4 with AgBF4, in anhydrous or wet thf, lead to [Ru2(μ-O2CC6H4-p-CMe3)4(thf)2]BF4 and [Ru2(μ-O2CC6H4-p-CMe3)4(thf)2]OH, respectively. The compounds are characterized by elemental analysis, magnetic measurements and spectroscopic techniques. The structure of [Ru2(μ-O2CC6H4-p-CMe3)4(thf)2]OH has been determined by X-ray crystallography. The compound has four bridging p-tertbutylbenzoate ligands with an RuRu distance of 2.260(1) Å; the coordination of each ruthenium atom is completed with a thf ligand which is occupying the axial position in the Ru25+ unit." @default.
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• W2056533151 date "1992-01-01" @default.
• W2056533151 modified "2023-10-03" @default.
• W2056533151 title "Synthesis and structure of a new complex of ruthenium containing the tetra(μ-tertbutylbenzoate)diruthenium(II,III) unit" @default.
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• W2056533151 doi "https://doi.org/10.1016/s0277-5387(00)83698-0" @default.
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