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- W2056533364 abstract "A facile two-step synthesis of natural germination inhibitor 5-butyl-3-oxo-2,3-dihydrofuran-2-yl-acetic acid [(+)-erigeronic acid A, 1] has been described via highly regioselective ring opening of (R)-acetoxysuccinic anhydride with the primary enolate of butyl methyl ketone, followed by an enzymatic hydrolysis and an in situ dehydrative cyclization pathway with 77% overall yield. On the basis of the present chemoenzymatic approach, (R)-configuration has been assigned to the C-2 chiral centre of the natural erigeronic acid." @default.
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- W2056533364 date "2006-03-01" @default.
- W2056533364 modified "2023-10-17" @default.
- W2056533364 title "A facile two-step chemoenzymatic access to natural germination inhibitor (+)-erigeronic acid A" @default.
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- W2056533364 doi "https://doi.org/10.1016/j.tet.2006.01.044" @default.
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