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- W2056533979 abstract "Free Radical Reactions of N-Heterocyclic Compounds, XIV[1]. - Oxidative Cyclization of Anilinopyrazoles to Pyrazolo[1,5-a]benzimidazoles1 Herrn Professor Christoph Rüchardt zum 65. Geburtstag gewidmet. Substituted Anilinopyrazoles 1 were oxidized by dibenzoyl peroxide or lead(IV) oxide. Different oxidation products were isolated depending on the substituents in the anilino group of anilinopyrazoles 1. Intermediate pyrazolyl radicals 5, which could be trapped by triphenylmethyl or phenoxyl radicals, undergo cyclization reaction with formation of pyrazolo[1,5-a]benzimidazoles 4. The structures of compounds 4 were proven by 1H- and 13C-NMR spectroscopy, 15N labeling and transformation of 4e to the betain 7e." @default.
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- W2056533979 date "1994-09-01" @default.
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- W2056533979 title "Oxidative Cyclisierung von Anilinopyrazolen zu Pyrazolo[1,5-a]benzimidazolen" @default.
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- W2056533979 doi "https://doi.org/10.1002/cber.19941270924" @default.
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