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- W2056535844 abstract "Acetonitril und Essigsäure-äthylester lassen sich durch photosensibilisierte Addition mittels Sensibilisatoren wie Acetophenon oder Benzol mit Triplettenergien von mindestens 72 kcal/mol in guten Ausbeuten an Norbornen zu den entsprechenden 2-exo-Norbornanderivaten 3 addieren. Im Gegensatz zu anderen photoinduzierten Additionen an ungesättigte Kohlenwasserstoffe erfolgen die untersuchten Reaktionen über den Triplettzustand des Olefins (Norbornen). Photosensitized Addition of Acetonitrile to Norbornene Acetonitrile and ethyl acetate are added to norbornene to yield the corresponding 2-exo-norbornane derivatives 3 by a photosensitized reaction involving sensitizers such as acetophenone or benzene with triplett energies higher than 72 kcal/mol. These reactions, in contrast to other photo-initiated free radical additions to olefins, involve the triplet olefin (norbornene) as reactive intermediate." @default.
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- W2056535844 date "1974-12-01" @default.
- W2056535844 modified "2023-10-17" @default.
- W2056535844 title "Photosensibilisierte Addition von Acetonitril an Norbornen" @default.
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- W2056535844 doi "https://doi.org/10.1002/jlac.197419741121" @default.
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