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- W2056538057 abstract "Die Bromwasserstoffabspaltung aus den bisher als 4,4-Dibrom-Verbindungen aufgefaßtennormalen Dibrom-3-ketosteroiden führt zur Bildung von 1,4-Dien-3-onen (IV), welche bisher nur aus 2,4-Dibrom-3-ketoallosteroiden erhalten worden waren. Daneben entstehen kleine Mengen von Δ1-2-Brom-3-ketonormal-steroiden (V). Die Ergebnisse der vorliegenden Arbeit, die überdies durch UV- und Infrarotspektren gestützt sind, machen es äußerst wahrscheinlich, daß die Dibromierung dernormalen 3-Ketosteroide in 2,4-Stellung erfolgt. Die in dieser Arbeit beschriebene Herstellung von 1,4-Dien-3-onen (IV) der Steroid-Reihe erweist sich somit als eine zweite Methode1 zur partiellen Synthese östrogener Hormone, ausgehend von Steroiden dernormalen Serie." @default.
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- W2056538057 date "1951-03-01" @default.
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- W2056538057 title "Steroids XV1. The bromination of 3-ketosteroids of the normal series" @default.
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- W2056538057 doi "https://doi.org/10.1007/bf02165553" @default.
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