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- W2056540547 abstract "A thermocoloration system consisting of a fluorane leuco dye (FR) and an iodonium salt (DPIOB) was investigated. The color for the FR/DPIOB system posseses a highly colored stability. The rates of the color development reaction show a rapid rise with increase in temperature, and, owing to two kinds of different activation energy (Ea) at the range of reaction temperature in the polymeric film, the reaction easily occurs in the high temperature region (>104°C). The thermal susceptibility increases with increase of FR/DPIOB content. A mechanism of thermocoloration via an electron transfer process is proposed. FR is oxidized to the FR+• radical, the iodonium cation is reduced to the diphenyl iodine radical, which then rapidly decomposes to iodobenzene and the phenyl radical. The ring opened cationic ester (FR-Ph) is formed by radical coupling between FR+• and the phenyl radical." @default.
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- W2056540547 date "1998-03-01" @default.
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- W2056540547 title "Electron transfer coloration of fluorane leuco dyes with iodonium salt—an approach for color stabilization" @default.
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- W2056540547 doi "https://doi.org/10.1016/s0143-7208(97)00031-4" @default.
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