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• W2056541010 startingPage "3169" @default.
• W2056541010 abstract "The paramagnetic heterocycles (R = 2,6-dimethylphenyl (1), 2,4,6-trimethylphenyl (2), and 2,6-diisopropylphenyl (3)) were obtained by reaction of “GaI” with Xyl-dab (N,N‘-bis[2,6-dimethylphenyl]-1,4-diazabuta-1,3-diene), Mes-dab (N,N‘-bis[2,4,6-trimethylphenyl]-1,4-diazabuta-1,3-diene), and Dipp-dab (N,N‘-bis[2,6-diisopropylphenyl]-1,4-diazabuta-1,3-diene), respectively. Compounds 1−3 were characterized structurally by X-ray crystallography. ESR investigations of 3 and quantum chemical calculations for the parent system were carried out to provide information on the bonding. The reaction of 1 with 1 equiv of the 1,4-dilithiated Xyl-dab led to the formation of Ga(Xyl-dab)2 (4) with one singly and one doubly reduced ligand; this compound was also characterized by X-ray crystallography." @default.
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• W2056541010 date "2002-06-25" @default.
• W2056541010 modified "2023-10-18" @default.
• W2056541010 title "Reactivity of “GaI” Toward <i>N</i>-Substituted 1,4-Diazabuta-1,3-dienes: Synthesis and Characterization of Gallium Heterocycles Containing Paramagnetic Diazabutadiene Monoanions" @default.
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• W2056541010 doi "https://doi.org/10.1021/om0200510" @default.
• W2056541010 hasPublicationYear "2002" @default.
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