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- W2056547042 abstract "The (2-Py)2N− ligand shows much more conformational freedom than the (2-Py)2P− anion in aluminium coordination. The two isomers [Al{(NPy)Py}3] (1a) and [Al{(NPy)Py}2(Py2N)] (1b) were isolated, the former containing exclusively cis-trans ligands, and the latter cis-trans ligands together with a trans-trans ligand. The energy differences in the noncoordinated anions (2-Py)2E− (E = N, P) were determined by computational methods to be low in the amide. While the N⇄Al donor bond energy is appreciable (96 kJ/mol), that of the P⇄Al donor bond is much lower (45 kJ/mol). This explains why the P-analogous donor-acceptor complex to Et2Al (2-Py)2N⇄AlEt3 could never be isolated. The P-centred systems are much better π-donors to soft metals than σ-donors to hard metals. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)" @default.
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- W2056547042 date "2002-12-01" @default.
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- W2056547042 title "Experimental and Computational Study on a Variety of Structural Motifs and Coordination Modes in Aluminium Complexes of Di(2-pyridyl)amides and -phosphanides" @default.
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- W2056547042 doi "https://doi.org/10.1002/1099-0682(200212)2002:12<3222::aid-ejic3222>3.0.co;2-u" @default.
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