FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2056547897> ?p ?o ?g. }

• W2056547897 endingPage "220" @default.
• W2056547897 startingPage "213" @default.
• W2056547897 abstract "The sulfur tolerance of bulk Mo2C catalyst has been evaluated for dry methane reforming (DMR) at 1050 °C, in the presence of dimethethylsulfide (DMS) at sulfur concentrations as high as 500 ppm. In addition, the effect of coupling the exothermic partial oxidation of methane with the highly endothermic reforming reaction was also investigated. It was determined that both DMS decomposition and partial oxidation take place in the gas phase, upstream of the catalyst bed, with CS2 as the primary DMS decomposition product. The CS2 was found to reversibly adsorbs on the catalyst surface, resulting in a stable but decreased activity. This conclusion was corroborated by examining the effects of DMS concentration, temperature, and in situ regeneration, and all are consistent with the occurrence of reversible sulfur chemisorption. Evidence is also presented to show that sulfur adsorption during DMR changes the redox chemistry of the catalyst, resulting in a slow oxidation of the surface. On the other hand, stable activity was maintained with oxygen in the feed and is attributed to lower CO2 concentrations under these conditions. Comparison experiments with a supported Rh catalyst gave superior results with respect to sulfur tolerance during DMR, suggesting that sulfur poisoning of noble metal catalysts may not be a serious problem at the high temperatures used in methane reforming." @default.
• W2056547897 created "2016-06-24" @default.
• W2056547897 creator A5021403420 @default.
• W2056547897 creator A5026182489 @default.
• W2056547897 creator A5028576891 @default.
• W2056547897 creator A5034964837 @default.
• W2056547897 date "2004-11-01" @default.
• W2056547897 modified "2023-09-27" @default.
• W2056547897 title "The effects of sulfur and oxygen on the catalytic activity of molybdenum carbide during dry methane reforming" @default.
• W2056547897 cites W1605178602 @default.
• W2056547897 cites W1963595443 @default.
• W2056547897 cites W1971137365 @default.
• W2056547897 cites W1978970995 @default.
• W2056547897 cites W1979982499 @default.
• W2056547897 cites W1996036494 @default.
• W2056547897 cites W2009101586 @default.
• W2056547897 cites W2030873459 @default.
• W2056547897 cites W2031840847 @default.
• W2056547897 cites W2032759659 @default.
• W2056547897 cites W2041255207 @default.
• W2056547897 cites W2050257746 @default.
• W2056547897 cites W2074365134 @default.
• W2056547897 cites W2077355560 @default.
• W2056547897 cites W2085510171 @default.
• W2056547897 cites W2144270338 @default.
• W2056547897 cites W2147027050 @default.
• W2056547897 doi "https://doi.org/10.1016/j.apcata.2004.07.035" @default.
• W2056547897 hasPublicationYear "2004" @default.
• W2056547897 type Work @default.
• W2056547897 sameAs 2056547897 @default.
• W2056547897 citedByCount "46" @default.
• W2056547897 countsByYear W20565478972012 @default.
• W2056547897 countsByYear W20565478972013 @default.
• W2056547897 countsByYear W20565478972014 @default.
• W2056547897 countsByYear W20565478972015 @default.
• W2056547897 countsByYear W20565478972016 @default.
• W2056547897 countsByYear W20565478972017 @default.
• W2056547897 countsByYear W20565478972018 @default.
• W2056547897 countsByYear W20565478972020 @default.
• W2056547897 countsByYear W20565478972021 @default.
• W2056547897 countsByYear W20565478972022 @default.
• W2056547897 crossrefType "journal-article" @default.
• W2056547897 hasAuthorship W2056547897A5021403420 @default.
• W2056547897 hasAuthorship W2056547897A5026182489 @default.
• W2056547897 hasAuthorship W2056547897A5028576891 @default.
• W2056547897 hasAuthorship W2056547897A5034964837 @default.
• W2056547897 hasConcept C104577883 @default.
• W2056547897 hasConcept C110686534 @default.
• W2056547897 hasConcept C124681953 @default.
• W2056547897 hasConcept C150394285 @default.
• W2056547897 hasConcept C161790260 @default.
• W2056547897 hasConcept C178790620 @default.
• W2056547897 hasConcept C179104552 @default.
• W2056547897 hasConcept C185592680 @default.
• W2056547897 hasConcept C193015443 @default.
• W2056547897 hasConcept C194439259 @default.
• W2056547897 hasConcept C202189072 @default.
• W2056547897 hasConcept C20976626 @default.
• W2056547897 hasConcept C33790079 @default.
• W2056547897 hasConcept C43535742 @default.
• W2056547897 hasConcept C516920438 @default.
• W2056547897 hasConcept C518881349 @default.
• W2056547897 hasConcept C540031477 @default.
• W2056547897 hasConcept C7304416 @default.
• W2056547897 hasConcept C83155894 @default.
• W2056547897 hasConceptScore W2056547897C104577883 @default.
• W2056547897 hasConceptScore W2056547897C110686534 @default.
• W2056547897 hasConceptScore W2056547897C124681953 @default.
• W2056547897 hasConceptScore W2056547897C150394285 @default.
• W2056547897 hasConceptScore W2056547897C161790260 @default.
• W2056547897 hasConceptScore W2056547897C178790620 @default.
• W2056547897 hasConceptScore W2056547897C179104552 @default.
• W2056547897 hasConceptScore W2056547897C185592680 @default.
• W2056547897 hasConceptScore W2056547897C193015443 @default.
• W2056547897 hasConceptScore W2056547897C194439259 @default.
• W2056547897 hasConceptScore W2056547897C202189072 @default.
• W2056547897 hasConceptScore W2056547897C20976626 @default.
• W2056547897 hasConceptScore W2056547897C33790079 @default.
• W2056547897 hasConceptScore W2056547897C43535742 @default.
• W2056547897 hasConceptScore W2056547897C516920438 @default.
• W2056547897 hasConceptScore W2056547897C518881349 @default.
• W2056547897 hasConceptScore W2056547897C540031477 @default.
• W2056547897 hasConceptScore W2056547897C7304416 @default.
• W2056547897 hasConceptScore W2056547897C83155894 @default.
• W2056547897 hasIssue "1-2" @default.
• W2056547897 hasLocation W20565478971 @default.
• W2056547897 hasOpenAccess W2056547897 @default.
• W2056547897 hasPrimaryLocation W20565478971 @default.
• W2056547897 hasRelatedWork W1009690060 @default.
• W2056547897 hasRelatedWork W1981033841 @default.
• W2056547897 hasRelatedWork W2348123847 @default.
• W2056547897 hasRelatedWork W2355451972 @default.
• W2056547897 hasRelatedWork W2361490703 @default.
• W2056547897 hasRelatedWork W294903466 @default.
• W2056547897 hasRelatedWork W4230773223 @default.
• W2056547897 hasRelatedWork W4236374936 @default.
• W2056547897 hasRelatedWork W4245317202 @default.
• W2056547897 hasRelatedWork W4253151876 @default.

• next