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- W2056547917 abstract "Where A designates the dinegative 3-ketoglutarate ion and L indicates a trinegative species (likely the enolate ion), the following compounds have been obtained: Na 2 A, NaCuL.XH 2 O, MgA.XH 2 O, MnA.XH 2 O, CoA.XH 2 O, NiA.XH 2 O. Hydration numbers are uncertain. Stoichiometry of Cu(II) and Zn(II) compounds could not be established. Structures have been assigned on the basis of the infrared spectra. Na 2 A appears to be a simple ionic carboxylate. MgA, MnA, CoA, and NiA are assigned a similar structure, with unidentate carboxylate coordination and hydrogen-bonded coordination between the metal and the second carboxylate oxygen (through water). NaCuL is assigned a metal-bridged polymer structure. There is not significant metal interaction with the carbonyl oxygen in any of the proposed structures." @default.
- W2056547917 created "2016-06-24" @default.
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- W2056547917 date "1972-03-15" @default.
- W2056547917 modified "2023-09-25" @default.
- W2056547917 title "3-Ketoglutarates: Compounds with Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Mg, and Na" @default.
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- W2056547917 doi "https://doi.org/10.1139/v72-129" @default.
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