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- W2056550150 abstract "We report the vibronic and cation spectra of p-vinylaniline, which are recorded by using the resonant two-photon ionization and the mass-analyzed threshold ionization spectroscopic techniques. The band origin of the S1 ← S0 electronic transition appears at 31,490 ± 2 cm−1 and the adiabatic ionization energy is determined to be 59,203 ± 5 cm−1. Due to the nature of the substituent, the amino and vinyl groups lead to lower electronic excitation and ionization energies by a few thousand wave numbers. Most of the observed active modes result from the in-plane ring deformation and substituent-sensitive vibrations of this molecule in the electronically excited S1 and cationic ground D0 states. By comparing the frequencies of the observed active vibrations, one may conclude that the molecular geometry and the vibrational coordinates of these modes of the p-vinylaniline cation in the D0 state resemble those of the neutral species in the S1 state." @default.
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- W2056550150 date "2012-10-01" @default.
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- W2056550150 title "Resonant two-photon ionization and mass-analyzed threshold ionization spectroscopy of p-vinylaniline" @default.
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- W2056550150 doi "https://doi.org/10.1016/j.chemphys.2012.08.023" @default.
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