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- W2056551010 abstract "Dienes and diols having carbon numbers of 6 to 12 reacted with carbon monoxide to give mixtures of lactones, dicarboxylic acids and monocarboxylic acids in the presence of copper(I) carbonyl catalysts at room temperature and at 1 atm of carbon monoxide. Dienes and diols having carbon numbers larger than 10 gave isomers of dicarboxylic acid, the main component of which was tetramethyl-substituted tertiary carboxylic acid. The yield increased for an increase of the carbon number. All starting materials gave mixtures of 1,4- and 1,5-lactones. Larger amounts of the lactones were obtained from diols than from dienes. Cyclic monocarboxylic acid and saturated monocarboxylic acid were obtained by the carbonylation of 1,7-octadiene. The appropriate reaction temperature of the dienes and diols was 0–10 and 20–30 °C respectively." @default.
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- W2056551010 date "1976-11-01" @default.
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- W2056551010 title "Carbonylation of Dienes and Diols in the Presence of Copper(I) Carbonyl Catalysts" @default.
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- W2056551010 doi "https://doi.org/10.1246/bcsj.49.3291" @default.
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