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- W2056551791 abstract "β-Hydroxy alkenes (such as methyl ricinoleate) furnish 1,2-epoxides by the normal epoxidation process but γ-hydroxy alkenes (such as methyl 9-hydroxyoctadec-cis-12-enoate and methyl threo-12,13-dihydroxyoleate), under the same reaction conditions, give 1,4-epoxides. The epoxidation of β- and γ-oxo alkenes gives mixed products, some of which are not stable. The rearrangement of methyl 9,10-epoxy-12-hydroxystearate (9,12-epoxide) and of methyl 9,10;12,13-diepoxystearate (dioxo and furanoid esters), under the influence of boron trifluoride, gives the products indicated. A 9,12 C18 furanoid ester is also formed by the reaction of methyl trans-11,12-epoxyoctadec-9-ynoate with aqueous methanolic acidic mercuric sulphate." @default.
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- W2056551791 date "1971-12-01" @default.
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- W2056551791 title "Fatty acids, Part 31 The formation of some substituted vic-epoxyoctadecanoates and their conversion to 1,4-epoxides and other compounds" @default.
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- W2056551791 doi "https://doi.org/10.1016/0009-3084(71)90007-7" @default.
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