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- W2056553041 abstract "Reaction of [(κ2-P,N)–Me2N(CH2)3PPh2]PtMe2 [(P∩N)PtMe2] with HSiR3 (triethylsilane or diphenylmethylsilane) results in the formation of MeSiR3 and the methyl silyl complexes (P∩N)Pt(Me)SiR3. In the early stages of the reaction, the hydrido complex (P∩N)Pt(Me)H is additionally observed. In the reaction of HSiMePh2, the rearranged complex (P∩N)Pt(Ph)SiMe2Ph is also formed. The reactivity of the complexes (P∩N)PtMe2 is influenced by the kind of chelating P∩N ligand and appears to depend on how easily the amino group is de-coordinated." @default.
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- W2056553041 date "2003-11-01" @default.
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- W2056553041 title "Reaction of hydrogenosilanes with dimethyl Pt(II) complexes promoted by hemilabile P,N-chelating ligands" @default.
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- W2056553041 doi "https://doi.org/10.1016/s0022-328x(03)00732-0" @default.
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