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- W2056554716 abstract "Heteronuclear complexes of the type Ln′xLn″1 –x[Co(CN)6]·nH2O have been synthesized for potential applications in solid oxide fuel cells. SmxEr1 –xCo and SmxYb1 –xCo complexes crystallize in the orthorhombic system, as do LaxSm1 –xCo complexes for x= 0-0.6. A plot of the lattice parameters of the orthorhombic structures of the complexes as a function of reff[xrLn′+(l -x)rLn′] shows linear behaviour similar to that observed for the LnCo complexes. For the decomposed products, perovskite-type Ln′xLn″1 –xCoO3 oxides are obtained. The crystal structure of Ln′xLn″1 –xCoO3 is orthorhombic for 0.1080 < reff/nm < 0.1199 and hexagonal for reff > 0.1199 nm, while for reff < 0.1080 nm no perovskite-type oxide was formed. We suggest that the orthorhombic distortion parameter is greater than ca. 0.267 for reff < 0.1080 nm and therefore no perovskite-type oxide is formed." @default.
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- W2056554716 date "1996-01-01" @default.
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- W2056554716 title "Preparation and characterization of perovskite-type Ln′<sub>x</sub>Ln″<sub>1–x</sub>CoO<sub>3</sub>for electroceramic applications" @default.
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- W2056554716 doi "https://doi.org/10.1039/jm9960601355" @default.
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