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- W2056557733 abstract "Three eremophilane sesquiterpenes (1, 2, and 3) were isolated from Penicillium roqueforti DAOM 232127, and their structures were established. The new (3S)-3-acetoxyeremophil-1(2),7(11),9(10)-trien-8-one (3) is a likely biosynthetic precursor of PR toxin. 1-Hydroxyeremophil-7(11),9(10)-dien-8-one (1) is related to the immunosuppressant cuspidatol. The application of semihyphenated LC-MS-SPE/NMR to rapidly identify, purify, and elucidate the structures of 1, 2, and 3 is described." @default.
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- W2056557733 date "2006-12-22" @default.
- W2056557733 modified "2023-10-02" @default.
- W2056557733 title "Isolation and Structure Elucidation by LC-MS-SPE/NMR: PR Toxin- and Cuspidatol-Related Eremophilane Sesquiterpenes from <i>Penicillium </i><i>roqueforti</i>" @default.
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- W2056557733 doi "https://doi.org/10.1021/np060454v" @default.
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