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- W2056560571 abstract "A comprehensive analysis of the nature of metal−carbon bonding in group 6 metallacyclobutadienes has been carried out by means of energy decomposition analysis and topological properties of electron density. The results suggest strong σ- and π-bonding interactions between the metal and the β-carbon (direct 1,3-metal−carbon bonding) as well as the existence of the β-carbon in a new type of planar tetracoordinate state characterized by a “catastrophe” bonding interaction with the metal. The importance of this bonding for alkyne metathesis is indicated." @default.
- W2056560571 created "2016-06-24" @default.
- W2056560571 creator A5033413160 @default.
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- W2056560571 date "2010-06-24" @default.
- W2056560571 modified "2023-09-27" @default.
- W2056560571 title "Direct 1−3 Metal−Carbon Bonding and Planar Tetracoordinated Carbon in Group 6 Metallacyclobutadienes" @default.
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- W2056560571 doi "https://doi.org/10.1021/om100260p" @default.
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