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- W2056565466 abstract "We employ Brillouin light scattering to measure the longitudinal modulus in supported thin polymer films in the direction normal to the film surface. In this first systematic experimental investigation, a reflection scattering geometry was utilized to probe elastic excitations localized between the free surface and the glass substrate, thus providing a direct access to the elastic constant along this direction. Thin supported polystyrene and poly(methyl methacrylate) films with thickness in the range of 40 nm−3 μm were explored. Comparison with the in-plane elastic constant obtained from the same optical technique but in transmission scattering geometry [Macromolecules 2007, 40, 7283] revealed no prominent directional tendency of the elastic properties with thickness. Nevertheless, there is now an experimental tool to address direction-dependent elastic constants in supported thin films." @default.
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- W2056565466 date "2009-07-31" @default.
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- W2056565466 title "Out-of-Plane Longitudinal Elastic Modulus of Supported Polymer Thin Films" @default.
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- W2056565466 doi "https://doi.org/10.1021/ma901246y" @default.
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