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• W2056567641 abstract "The Stone-Wales (pyracylene) rearrangement is a hypothetical mechanism for interconversion of fullerene isomers, accounting for mobility of the pentagons on the surfaces of these clusters. Two versions of the transformation, involving patches of 4 and 12 rings, respectively, can be defined. Energetic and group-theoretical aspects of the transformation are discussed, symmetry-based selection rules devised and complete isomerisation maps presented for small fullerenes (C20 to C40) and isolated-pentagon isomers (C78 to C88). Fullerenes that self-racemise under this transformation include D2 C28. Limitations on the usefulness of this mechanism as a means of rationalising experimental isomer distributions are briefly discussed." @default.
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• W2056567641 date "1992-01-01" @default.
• W2056567641 modified "2023-10-16" @default.
• W2056567641 title "Isomerisations of the fullerenes" @default.
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• W2056567641 doi "https://doi.org/10.1016/0008-6223(92)90065-5" @default.
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