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- W2056567758 abstract "We have developed a simple theory within the Rayleigh–Gans–Debye (RGD) approximation to follow the homocoagulation process by a turbidity measurement. We have considered all the contributions in the aggregate from particle–particle pairs, with none, one and two particles between them and a von Smoluchowski process. It has been possible to obtain a theoretical description of the experimental absorbance vs. time curves for the first minute in most general cases. Due to the dependence on the RGD approximation, the smaller the particle is, the better agreement between experimental data and theoretical calculations is obtained. We have used this model to develop a technique to calculate kinetic constants from experimental turbidity measurements from homocoagulation of polystyrene latexes. Great agreement has been found between kinetic constants obtained by this method and others by fitting the initial slope. In this new method we can adjust up to 60 s of experimental data (for the particle concentrations we have used), to be compared with 4 or 5 s that can be used in adjusting the initial slope in the classical turbidimetric technique." @default.
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- W2056567758 date "1998-09-01" @default.
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- W2056567758 title "Theoretical description of the absorbance versus time curve in a homocoagulation process." @default.
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- W2056567758 doi "https://doi.org/10.1016/s0927-7757(97)00264-1" @default.
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