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- W2056569676 abstract "A unstable intermediate product with peak absorbance at 494 nm was found in the reaction of cyanide with pyridine-barbituric acid reagent. The intermediate was applied to the determination of cyanide by reagent-injection flow-injection analysis. The calibration graph was linear over the range of 0-4-mu-g ml-1 cyanide and the detection limit was 20 ng ml-1 cyanide; the relative standard deviation at 1.0-mu-g ml-1 was 0.6% (n = 16) and the sampling rate was 60 h-1. Interference studies showed that the main interferents are Co2+, Ni2+, SCN-, I- and formaldehyde. The proposed method was applied successfully to determine free cyanide in natural and waste water samples." @default.
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- W2056569676 date "1992-05-01" @default.
- W2056569676 modified "2023-09-23" @default.
- W2056569676 title "Flow-injection determination of cyanide by detecting an intemediate of the pyridine-barbituric acid chromgonic reaction" @default.
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- W2056569676 doi "https://doi.org/10.1016/0003-2670(92)80198-g" @default.
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